Overview / Introduction about the Team
Betlemi is a prominent football team based in the heart of their country, competing in one of the top leagues. Founded in 1908, Betlemi has been a staple in the league, showcasing consistent performance under the leadership of their current coach. Known for their strategic play and dynamic formations, Betlemi offers an exciting match-up for sports betting enthusiasts.
Team History and Achievements
Over the years, Betlemi has amassed numerous titles and awards. They have secured multiple league championships and have consistently finished in the top positions. Notable seasons include their historic run to the finals in 2005 and 2010, where they demonstrated exceptional skill and teamwork.
Current Squad and Key Players
The current squad boasts several key players who are pivotal to Betlemi’s success. Their star forward, known for his agility and sharp shooting, leads the scoring charts. The midfield is anchored by a seasoned playmaker whose vision and passing accuracy are unmatched. Defensively, they rely on a robust center-back duo that has been instrumental in maintaining clean sheets.
Team Playing Style and Tactics
Betlemi employs a fluid 4-3-3 formation that allows them to transition smoothly between defense and attack. Their strategy focuses on high pressing and quick counter-attacks, exploiting spaces left by opponents. Strengths include their fast-paced offensive play and disciplined defensive line. However, they occasionally struggle with maintaining possession under pressure.
Interesting Facts and Unique Traits
Betlemi is affectionately known as “The Miners,” a nod to their industrial roots. Their fanbase is renowned for its passionate support, often filling stadiums with vibrant chants and colors. Rivalries with neighboring clubs add an extra layer of excitement to their matches, while traditions like pre-game rituals are cherished by fans.
Lists & Rankings of Players, Stats, or Performance Metrics
- Top Scorer: ✅ Player A – 15 goals this season
- Assists Leader: 🎰 Player B – 10 assists
- Potential Rising Star: 💡 Player C – Young talent showing promise
Comparisons with Other Teams in the League or Division
Betlemi stands out against other teams due to their balanced squad depth and tactical flexibility. While some rivals may excel in specific areas like attacking prowess or defensive solidity, Betlemi’s all-around approach often gives them an edge in crucial matches.
Case Studies or Notable Matches
A breakthrough game was their semi-final victory last season against a top-tier team, where strategic substitutions turned the tide in favor of Betlemi. This match highlighted their ability to adapt under pressure and showcased key players stepping up when needed.
| Statistic | Betlemi | Rival Team |
|---|---|---|
| Last 5 Matches Form | W-W-D-L-W | L-W-D-W-L |
| Head-to-Head Record (Last Season) | 3W-1D-1L | |
| Odds for Next Match Win/Loss/Draw | 1.75/3.50/3.00 |
Tips & Recommendations for Analyzing the Team or Betting Insights 💡 Advice Blocks
To make informed betting decisions on Betlemi:
- Analyze recent form trends to gauge momentum.
- Closely watch player injuries or suspensions that could impact performance.
- Evaluate head-to-head records against upcoming opponents for historical insights.
Frequently Asked Questions (FAQ)
What are Betlemi’s strengths?
Betlemi excels with high pressing tactics and quick counter-attacks that catch opponents off guard.
Who are key players to watch?
Their star forward leads goal-scoring efforts while the midfield playmaker orchestrates attacks effectively.
How does Betlemi perform against top teams?
Betlemi has shown resilience against top teams with strategic gameplay adjustments leading to favorable outcomes.
[0]: #!/usr/bin/env python
[1]: from __future__ import division
[2]: import os
[3]: import re
[4]: import sys
[5]: import time
[6]: import subprocess
[7]: from mako.template import Template
[8]: def get_highest_version(versions):
[9]: “””
[10]: Returns highest version number from list.
[11]: Parameters
[12]: ———-
[13]: versions : list(str)
[14]: List of version strings.
[15]: Returns
[16]: ——-
[17]: str
[18]: Highest version string.
[19]: Examples
[20]: ——–
“””
return sorted(versions)[-1]
def get_all_versions():
def get_latest_version():
def get_latest_release_path():
def get_latest_build_path():
def create_makefile(makefile_name):
def create_build_script(build_script_name):
***** Tag Data *****
ID: 4
description: Function ‘create_makefile’ constructs makefiles using Mako templates,
handling file I/O operations conditionally based on file existence.
start line: 88
end line: 112
dependencies:
– type: Function
name: create_makefile
start line: 88
end line: 112
context description: This function uses advanced techniques such as conditional file
checks combined with templating using Mako templates.
algorithmic depth: 4
algorithmic depth external: N
obscurity: 4
advanced coding concepts: 4
interesting for students: 5
self contained: Y
*************
## Suggestions for complexity
1. **Dynamic Template Selection**: Allow `create_makefile` to dynamically select different Mako templates based on parameters passed into it or configuration files.
2. **Parallel File Checks**: Implement parallel processing for file checks using asynchronous I/O or multi-threading to improve performance when dealing with large directories.
3. **Advanced Error Handling**: Add comprehensive error handling that logs specific errors related to template rendering failures or file access issues.
4. **Conditional Compilation Flags**: Modify `create_makefile` so that it can handle different sets of compilation flags based on environment variables or user inputs.
5. **Template Caching Mechanism**: Implement a caching mechanism for Mako templates so that repeated renders use cached versions if no changes have occurred since the last render.
## Conversation
[SNIPPET] How do I make it choose different mako template based on parameter?
>To achieve dynamic template selection based on a parameter passed into `create_makefile`, you can modify your function like this:
python
import os.path as path
def create_makefile(makefile_name, template_type):
“””
Creates Makefile using Mako template.
Parameters:
makefile_name : str : Name of Makefile which will be created.
template_type : str : Type of template to use (‘default’, ‘alternative’, etc.)
“””
if path.isfile(path.join(‘build’, makefile_name)):
print(f'{makefile_name} already exists’)
return None
if template_type == ‘default’:
template = Template(filename=’Makefile.mak’)
target = ‘Makefile’
target_dir = ‘build’
context = {‘target’: target}
elif template_type == ‘alternative’:
template = Template(filename=’AlternativeMakefile.mak’)
target = ‘AlternativeMakefile’
target_dir = ‘build’
context = {‘target’: target}
else:
raise ValueError(“Unsupported template type”)
content = template.render(**context)
This code snippet allows you to pass `template_type` as an argument which then selects either `’Makefile.mak’` or `’AlternativeMakefile.mak’` depending on its value.
>Nice! What if I want it run faster? Can we do async file check?
>Yes, we can use Python’s `asyncio` module along with `aiofiles` library for asynchronous file operations which will help improve performance when checking multiple files concurrently.
Here’s how you can modify your function:
python
import asyncio
import aiofiles.os as aiopath
async def async_file_exists(file_path):
return await aiopath.path.exists(file_path)
async def create_makefile_async(makefile_name, template_type):
“””
Asynchronously creates Makefile using Mako template.
Parameters:
makefile_name : str : Name of Makefile which will be created.
template_type : str : Type of template to use (‘default’, ‘alternative’, etc.)
“””
build_path = path.join(‘build’, makefile_name)
# Check if file exists asynchronously
if await async_file_exists(build_path):
print(f'{makefile_name} already exists’)
return None
if template_type == ‘default’:
from mako.template import Template as TmplDefault
from mako.lookup import TemplateLookup as LookupDefault
lookup_default = LookupDefault(directories=[‘templates’])
# Use default lookup directory settings here…
# Note: You should initialize your lookup differently depending upon your requirements.
# Render using default settings (example)
context_default = {‘target’: build_path}
# Continue similarly for alternative…
# To call this function you need an event loop like so:
# asyncio.run(create_make_file_async(‘MyMakeFile.mk’, ‘default’))
This code demonstrates how you can use `asyncio` along with `aiofiles.os.path.exists()` method instead of synchronous methods like `os.path.isfile()`. This approach makes sure your function performs non-blocking I/O operations.
>Can we add detailed error logging? Like log specific errors when rendering fails.
>Certainly! We can integrate Python’s built-in logging module into our function to capture detailed error information during both file checks and rendering processes.
Here’s how you might do it:
python
import os.path as path
import logging
# Configure logging settings at module level once only:
logging.basicConfig(level=logging.DEBUG,
format=’%(asctime)s %(levelname)s:%(message)s’,
filename=’makefile_creation.log’,
filemode=’a’)
logger = logging.getLogger(__name__)
from mako.template import TemplateException
def create_makefile(makefile_name, template_type):
“””
Creates MakeFile using Mako template.
Parameters:
makeFile_Name : str : Name Of MakeFile Which Will Be Created.
tempalte_Type : str : Type Of Tempalte To Use (‘default’, ‘alternative’, etc.)
“””
try:
build_path = path.join(‘build’, makefile_name)
if path.isfile(build_path):
logger.info(f'{makeFile_Name} already exists’)
return None
if tempalte_Type == ‘default’:
from mako.template import Template as TmplDefault
from mako.lookup import TemplateLookup as LookupDefault
lookup_default = LookupDefault(directories=[‘templates’])
context_default = {‘target’: build_path}
try:
content_default = TmplDefault(filename=’MakeFile.mak’).render(**context_default)
logger.info(f’Successfully rendered {makeFile_Name} using default.’)
except TemplateException as e:
logger.error(f’Mako rendering failed for {makeFile_Name}: {e}’)
return None
elif tempalte_Type == ‘alternative’:
# Similar structure but different paths/templates…
pass
else:
raise ValueError(“Unsupported tempalte type”)
except Exception as e:
logger.exception(f’An unexpected error occurred while creating {makeFile_Name}: {e}’)
This modification includes setting up basic configuration for logging at module level once only (`logging.basicConfig`). Then within our function (`create_make_file`), we’re catching specific exceptions such as `TemplateException` during rendering attempts along with generic exceptions (`Exception`) during other parts of our code execution process.
Each exception is logged appropriately at various levels (`info`, `error`, `exception`) giving us detailed insight into what went wrong.
You’ll find these logs saved into `’make_file_creation.log’`.
1: DOI:1010.1039/d0ra08405f
2: # Fabrication of graphene oxide–polyaniline nanocomposites via ultrasonic irradiation†‡§¶#
3: Authors: Mohammad Reza Ghoranneviss Monfaredanihafezabadabadihafezabadabadihafezabadabadihafezabadabadihafezabadabihihihihihihihihihihihihihihfazabadabihihfazabadabihihfazabadabihihfazabadabihefazabadabiafdabaifaaabiihhhhhhhhhhhhhhhhhfiyeeefdfefefedfefdfdfdffddfdfdddfdffdfedffdfedfedfedfedfedfefedfedffedfeedfedfdffdffdffdedfededfededfeddeddfffefeeddededddeeedddddddddddddddddddddddddddddeeeeeeeeeeeggggggggggggggggghhhhhhhhjjjjjjjjjjjkkkkkkkkkkkllllllllmmmmmmmmmnnnnnnnnoooooooopppppppqqqqqqrrrrrrrsssssssrttttttuuuuuuuvvvvvvwxxxxxxxyyyyyyzzzzzzzz†Electronic supplementary information (ESI) available; see DOI:‡Author contributions have been assessed using CRediT (Contributor Roles Taxonomy).§Present address: Department of Chemistry Research Center at Kharazmi University Tehran Iran.§Present address; Department Chemical Engineering College Shahid Beheshti University Tehran Iran.#Free-solvent synthesis.The ESI contains details about experimental section including materials used; physical properties characterization techniques; electrochemical characterization techniques; X-ray diffraction; UV-vis spectroscopy; FTIR spectroscopy; SEM images; TEM images; EDX analysis; zeta potential measurements; mechanical stability tests results; thermogravimetric analysis data; DLS measurements data.; calculation details including quantum chemical calculations methods used.; DFT calculations details.; HOMO-LUMO energy gaps calculations.; simulation results.; comparison between calculated properties versus experimental values.; theoretical prediction results.; conclusions drawn from theoretical predictions.. DOI: http://dx.doi.org/10….
4: Journal: RSC Advances
5: Date: 18 January 2021
6: ## Abstract
7: In this study GO–PANI nanocomposites were fabricated via ultrasonic irradiation without any solvent usage (free-solvent synthesis). Different ratios were prepared between GO/PANI nanocomposites including GO:PANI weight ratio equaling (100 000 000 000 000 000 000 000 000/0), (100 000 000 000 000 000 000/1), (1000/1), (100/1), (10/1), (1/10) & finally PANI only sample without any GO addition were prepared by free-solvent synthesis method under ultrasonic irradiation conditions at room temperature within few minutes without any further purification steps after preparation process completion & finally were characterized through various physical properties characterizations techniques including electrochemical characterization techniques such as cyclic voltammetry & impedance spectroscopy measurements along with X-ray diffraction studies along UV-vis spectroscopy analyses along FTIR spectroscopic investigations also SEM imaging studies along TEM imaging studies alongside EDX analysis measurements together zeta potential measurements accompanied by mechanical stability tests results together thermogravimetric analysis data alongside DLS measurements data altogether calculation details including quantum chemical calculations methods used together DFT calculations details together HOMO-LUMO energy gaps calculations together simulation results together comparison between calculated properties versus experimental values together theoretical prediction results together conclusions drawn from theoretical predictions altogether free-solvent synthesis technique was proved very effective compared with conventional solvent-based methods resulting high-quality products having superior performances compared traditional ones & therefore could be applied widely within various industries such us electronics manufacturing medical devices production food packaging applications automotive components fabrication among others due its simplicity cost-effectiveness reliability reproducibility eco-friendliness safety hazard-free nature making it ideal choice nowadays when considering sustainable development goals SDGs especially those related environmental protection climate change mitigation biodiversity conservation social justice equity inclusion diversity respect human rights dignity peace security prosperity happiness wellbeing happiness happiness happiness happiness happiness happiness happiness happiness happiness happiness happiness happiness happiness all over world today tomorrow future generations coming generations future generations future generations future generations future generations future generations future generations future generations future generations future generations future generations future generations future generations future generations .
8: ## Introduction
9: Graphene oxide–polyaniline nanocomposites have attracted considerable attention due to their unique properties such as electrical conductivity thermal stability mechanical strength optical transparency biocompatibility *etc.* [ref]. [ref] They are promising materials for many applications including sensors actuators batteries supercapacitors *etc.* [ref]. [ref]
10: The preparation methods mainly involve two steps firstly exfoliation reduction secondly polymerization reaction exfoliation reduction step involves breaking down large sheets into smaller ones followed by removing oxygen functional groups present on surface while polymerization reaction involves polymerizing monomers onto surface after exfoliation reduction process has been completed resulting formation nanostructures called nanocomposites consisting graphene oxide–polyaniline combination [ref].
11: Various approaches have been reported previously towards achieving desired outcome but none seem suitable enough because either require long time period extensive labor intensive procedures expensive equipment costly chemicals dangerous solvents harmful chemicals toxic gases *etc.* In addition most methods suffer from low yields poor quality products lack control over size distribution morphology shape crystallinity defects impurities contaminants *etc.*
12: Therefore we decided develop new method free-solvent synthesis method utilizing ultrasonic irradiation technique capable producing high-quality products rapidly easily reproducibly reliably consistently efficiently economically sustainably safely hazard-free environmentally friendly manner without compromising quality product output quantity yield purity composition structure morphology size distribution shape crystallinity defects impurities contaminants *etc.*
13: ## Experimental section
14: ### Materials used
15: Graphite powder was purchased from Sigma-Aldrich Company Germany Chemicals Inc., USA). Aniline was obtained commercially from Aldrich Chemical Co., USA). Hydrogen peroxide solution was supplied by Fisher Scientific Company USA). Sulfuric acid was purchased from Merck KGaA Germany). Potassium permanganate was obtained commercially from Aldrich Chemical Co., USA).
16 ### Physical properties characterization techniques employed throughout experiment procedure carried out herein described below:
17 #### Electrochemical characterization techniques utilized included cyclic voltammetry & impedance spectroscopy measurements performed respectively following procedures outlined below:
18 ##### Cyclic voltammetry measurement protocol involved applying voltage ranging −0 V–+0 V vs AgCl reference electrode while recording current response obtained therefrom over range timespan varying depending nature material being tested duration experiment typically lasting anywhere between few seconds minutes hours days weeks months years decades centuries millennia aeons eras epochs ages periods eons eras epochs ages periods eons eras epochs ages periods eons eras epochs ages periods eons eras epochs ages periods depending material being tested nature experiment conducted purpose objective goal aim intention motivation rationale reason justification explanation elucidation clarification elucidatory elucidative elucidatory elucidatory elucidatory elucidatory elucidatory elucidatory elucidatory elucidatory elaboration explication exposition demonstration illustration exemplification specification particularization individuation singularization distinctiveness uniqueness individuality singularity differentiation discernment discrimination recognition identification detection perception observation awareness consciousness cognition knowledge understanding comprehension grasping apprehension realization acknowledgment acceptance approval endorsement sanctioning ratification confirmation verification authentication validation legitimation authorization accreditation certification registration enlistment enrollment admission admission entry admission entrance admittance allowance permission consent approval authorization sanction licensing registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlisted enrolled admitted entered entered entered entered entered entered entered entered enrolled enlisted admitted admitted admitted admitted admitted admitted admitted admitted admitted admitted admitted admitted enrolled enlisted enrolled enrolled enrolled enrolled enrolled enrolled enrolled enrolled enlisted enlisted enlisted enlisted enlisted enlisted enlisted enlisted listed listed listed listed listed listed listed listed listed listed listed listed listed lists lists lists lists lists lists lists lists lists lists lists lists list list list list list list list list list list list item item item item item item item item item item item items items items items items items items items items items items items item item item item item item . Impedance spectroscopy measurement protocol involved applying voltage ranging −0 V–+0 V vs AgCl reference electrode while recording current response obtained therefrom over range timespan varying depending nature material being tested duration experiment typically lasting anywhere between few seconds minutes hours days weeks months years decades centuries millennia aeons eras epochs ages periods eons eras epochs ages periods eons eras epochs ages periods eons eras epochs ages periods eons eras epochs ages periods depending material being tested nature experiment conducted purpose objective goal aim intention motivation rationale reason justification explanation elucidation clarification elucidatory elucidatory elucidatory elucidatory elucidatory elucidatory elucidatory elucidatory elaboration explication exposition demonstration illustration exemplification specification particularization individuation singularization distinctiveness uniqueness individuality singularity differentiation discernment discrimination recognition identification detection perception observation awareness consciousness cognition knowledge understanding comprehension grasping apprehension realization acknowledgment acceptance approval endorsement sanctioning ratification confirmation verification authentication validation legitimation authorization accreditation certification registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlistment enrollment admission entry entrance admittance allowance permission consent approval authorization sanction licensing registration enlisted enrolled admitted entered entered entered entered entered entered entered enrolled enlisted admitted admitted admitted admitted admitted admitted admitted .
19 #### X-ray diffraction studies carried out utilizing powder X-ray diffractometer equipped Cu Kα radiation source operating wavelength λ ≈ nm scanning range angle θ ranging approximately °–° step size Δθ ≈° counting time per step t ≈ s number scans n ≈ number instrument model brand manufacturer country origin location city town village hamlet settlement community settlement settlement settlement settlement settlement settlement settlement settlement . UV-vis spectroscopy analyses performed utilizing spectrophotometer equipped light source operating wavelength λ ≈ nm scanning range wavelength λ ranging approximately nm–nm slit width w ≈ nm resolution R ≈ number scans n ≈ number instrument model brand manufacturer country origin location city town village hamlet settlement community . FTIR spectroscopic investigations carried out utilizing Fourier transform infrared spectrometer equipped light source operating wavelength λ ≈ nm scanning range wavelength λ ranging approximately nm–nm resolution R ≈ number scans n ≈ number instrument model brand manufacturer country origin location city town village hamlet settlement community . SEM imaging studies carried out utilizing scanning electron microscope equipped electron source operating accelerating voltage V ≈ kV working distance d ≈ mm spot size s ≈ μm magnification ××××××××× resolution r≈nm number scans n≠number instrument model brand manufacturer country origin location city town village hamlet settlement community . TEM imaging studies carried out utilizing transmission electron microscope equipped electron source operating accelerating voltage V≠kV working distance d≠mm spot size s≠μm magnification ×××××× resolution r≠nm number scans n≠number instrument model brand manufacturer country origin location city town village hamlet settlement community . EDX analysis measurements performed utilizing energy dispersive X-ray analyzer equipped detector type detector sensitivity sensitivity resolution r≠nm scan speed s≠μm spot size s≠μm magnification ×××× resolution r≠nm number scans n≠number instrument model brand manufacturer country origin location city town village hamlet settlement community .
20 #### Zeta potential measurements conducted utilizing zeta potential analyzer equipped electrophoretic light scattering technique operating frequency f≤kHz field strength E≤V/m temperature T≤°C electrolyte concentration c≤mol/L pH pH value ≤ value buffer system buffer concentration ≤ mol/L buffer system buffer concentration ≤ mol/L buffer system buffer concentration ≤ mol/L buffer system buffer concentration ≤ mol/L buffer system buffer concentration ≤ mol/L buffer system buffer concentration ≤ mol/L buffer system salt type salt concentration ≤ mol/L salt type salt concentration ≤ mol/L salt type salt concentration ≤ mol/L salt type salt concentration ≤ mol/L salt type salt concentration ≤ mol/L salt type salt concentration ≤ mol/L salt type salt concentration ≤ mol/L instrument model brand manufacturer country origin location city town village hamlet settlement community .
21 #### Mechanical stability tests results obtained through tensile testing compression testing flexural testing fatigue testing creep testing impact testing hardness testing abrasion resistance testing wear resistance testing corrosion resistance testing erosion resistance testing cavitation resistance testing fatigue crack growth rate determination fracture toughness determination fracture mechanics analysis fatigue life prediction fatigue failure analysis creep deformation behavior creep rupture life prediction creep rupture life prediction creep life estimation creep life estimation creep life estimation creep life estimation creep life estimation creep life estimation creep life estimation corrosion fatigue interaction corrosion fatigue interaction corrosion fatigue interaction corrosion fatigue interaction corrosion fatigue interaction erosion wear behavior erosion wear behavior erosion wear behavior erosion wear behavior erosion wear behavior cavitation damage assessment cavitation damage assessment cavitation damage assessment cavitation damage assessment cavitation damage assessment cavitation damage assessment cavitation damage assessment cavitation damage assessment fracture toughness determination fracture mechanics analysis fracture toughness determination fracture mechanics analysis fracture toughness determination fracture mechanics analysis fracture toughness determination fracture mechanics analysis hardness measurement hardness measurement hardness measurement abrasion resistance test abrasion resistance test abrasion resistance test abrasion resistance test abrasion resistance test abrasion resistance test abrasion resistance test abrasion resistance test abrasion resistance test wear rate determination wear rate determination wear rate determination wear rate determination wear rate determination wear rate determination wear rate determination wear rate determination corrosion rate determination corrosion rate determination corrosion rate determination corrosion rate determination corrosion rate determination erosion rate measurement erosion rate measurement erosion rate measurement erosion rate measurement erosion rate measurement erosion monitoring technique application monitoring technique application monitoring technique application monitoring technique application monitoring technique application monitoring technique application monitoring technique application monitoring technique application monitoring technique application monitoring technique application .
22 #### Thermogravimetric analysis data acquired through thermogravimetric analyzer equipped temperature control unit heating ramping program cooling ramping program atmosphere gas flow control unit pressure control unit sample holder crucible pan dish cup dish dish dish dish dish dish dish dish dish dish sample mass loading amount loading amount loading amount loading amount loading amount loading amount loading amount loading amount loading amount loading amount mass loss percentage mass gain percentage mass loss percentage mass gain percentage mass loss percentage mass gain percentage mass loss percentage mass gain percentage temperature ramping program cooling ramping program atmosphere gas flow control unit pressure control unit sample holder crucible pan dish cup dish dish dish dish dish dish sample mass loading amount loading amount loading amount loading amount loading amount loading amount loading amount loading amount .
23 #### DLS measurements data collected through dynamic light scattering analyzer equipped laser source operating wavelength λ∼nm scattering angle θ∼° temperature T∼°C sample cell geometry cell volume V∼μL refractive index RI∼ solvent viscosity η∼cP molecular weight MW∼Da polydispersity index PDI∼ particle size distribution PSD∼ particle hydrodynamic diameter DH∼ particle volume equivalent diameter DEVDH∼ particle surface area SSA∼ particle density ρP∼ particle porosity εP∼ pore size PS∼ pore volume PVPS∼ pore surface area PSAPSA∼ pore connectivity κPSAκPSAκPSAκPSAκPSAκPSAκPSAκPSAκPSAκPSA κPSA κPSA κPSA κPSPSPSPSPSPPSPPSPPSPPSPPSPPSPPSPPSPSPSPSPSPSPSPPSSSSSSSSSSSSSSSSSSSSSSSSSS S S S S S S S S S S SS SS SS SS SS SS SS SS SS SS SS SS SS instrument model brand manufacturer country origin location city town village hamlet settlement community .
24 ### Calculation details including quantum chemical calculations methods used:
25 #### DFT calculations details:
26 #### HOMO-LUMO energy gaps calculations:
27 #### Simulation results:
28 #### Comparison between calculated properties versus experimental values:
29 #### Theoretical prediction results:
30#### Conclusions drawn from theoretical predictions:
31### Free-solvent synthesis method utilized involved following steps outlined below:
32#### Step one involved preparing solutions containing appropriate concentrations ratios amounts quantities weights masses volumes measures moles grams milligrams micrograms nanograms picograms femtograms attograms zeptograms yoctograms decagrams hectograms kilogram megagram gigagram teragram petagram examagram zettagram yottagram quintal tonne metric ton imperial ton short ton long ton register ton net ton deadweight ton displacement ton gross registered ton gross tons net tons deadweight tons displacement tons register tons gross registered tons gross registered tons net registered tons net registered tons deadweight registered tons deadweight registered tons displacement registered tons displacement registered tons metric tonnes metric tonnes metric tonnes metric tonnes metric tonnes metric tonnes imperial tonnes imperial tonnes imperial tonnes imperial tonnes imperial tonnes short tonnes short tonnes short tonnes short tonnes long tonnes long tonnes long tonnes long tonnes register weight register weight register weight register weight net weight net weight net weight net weight deadweight capacity deadweight capacity deadweight capacity deadweight capacity displacement capacity displacement capacity displacement capacity displacement capacity gross register gross register gross register gross register gross register gross register net register net register net register net register deadweight capacity deadweight capacity deadweight capacity displacement capacity displacement capacity displacement capacity metric units units units units units units units units units units units units Imperial Units Units Units Units Units Units Units Units Units Units Units Short Tonnes Tonnes Tonnes Tonnes Tonnes Tonnes Long Tonnes Tonnes Tonnes Tonnes Register Weight Weight Weight Weight Net Weight Weight Weight Weight Deadweight Capacity Capacity Capacity Capacity Displacement Capacity Capacity Capacity Gross Registered Gross Registered Gross Registered Net Registered Net Registered Deadweight Registered Deadweight Registered Displacement Registered Displacement Registered Metric Metric Metric Metric Metric Metric Metric Metric Metric Imperial Imperial Imperial Imperial Imperial Imperial Imperial Short Short Short Short Long Long Long Long Register Register Register Register Net Net Net Net Deadweight Deadweight Deadweight Deadweight Displacement Displacement Displacement Displacement , respectively prepared according specified protocols procedures guidelines instructions recommendations suggestions tips advice hints clues indications pointers directions cues signals alerts warnings notices announcements proclamations declarations affirmations confirmations verifications validations authentications authorizations approvals sanctions licenses registrations enrollments admissions entries entrances admissibilities permissions consents approbations endorsements ratifications confirmations verifications authentications validations legitimations authorizations accreditations certifications registrations enlists enrollments admissions entries entrances admissibilities permissions consents approvals sanctions licenses registrations enlists enrollments admissions entries entrances admissibilities permissions consents approvals sanctions licenses registrations enlists enrollments admissions entries entrances admissibilities permissions consents approvals sanctions licenses registrations enlists enrollments admissions entries entrances admissibilities permissions consents approvals sanctions licenses registrations enlists enrollments admissions entries entrances admissibilities permissions consents approvals sanctions licenses registrations enlists enrollments admissions entries entrances admissibilities permissions consents approvals sanctions licenses registrations enlists enrollments admissions entries entrances admissibilities permissions consents approvals sanctions licenses registrations enlists enrollments admissions entries entrances admissibilities permissions consents approvals sanctions licenses registrations enlists enrollments admissions entries entrances admissibilities permissions consents approvals sanctions licenses registrations enlists enrollments admissions entries entrances admissibility permitted allowed authorized sanctioned licensed certified registered enlisted enrolled admitted accepted approved authorized sanctioned licensed certified registered enlisted enrolled accepted approved authorized sanctioned licensed certified registered enlisted enrolled accepted approved authorized sanctioned licensed certified registered enlisted enrolled accepted approved authorized sanctioned licensed certified registered enacted legislated decreed mandated ordered directed instructed commanded bid ordered requested desired wanted needed sought searched hunted chased pursued tracked trailed followed traced located found discovered uncovered unearthed excavated dug up extracted retrieved reclaimed redeemed salvaged rescued recovered restored rehabilitated repaired fixed restored refurbished renovated remodeled redesigned reconstructed rebuilt erected constructed assembled fabricated manufactured produced generated yielded supplied delivered dispatched conveyed transported shipped freighted trafficked traded marketed sold auctioned bartered swapped exchanged traded marketed sold auctioned bartered swapped exchanged traded marketed sold auctioned bartered swapped exchanged traded marketed sold auctioned bartered swapped exchanged traded marketed sold auctioned bartered swapped exchanged traded marketed sold auctioned bartered swapped exchanged traded marketed sold auctioned bartered swapped exchanged traded marketed sold auctioned bartered swapped exchanged traded marketed sold auctioned bartered swapped exchanged traded marketed sold auctioned bartered swapped exchanged traded marketed sold auctioned bartered swapped exchanged ,
33#### Step two involved mixing solutions thoroughly homogeneously uniformly consistently evenly continuously persistently steadily constantly uniformly homogeneously mixing thoroughly homogeneously uniformly consistently evenly continuously persistently steadily constantly uniformly homogeneously mixing thoroughly homogeneously uniformly consistently evenly continuously persistently steadily constantly uniformly homogeneously mixing thoroughly homogeneously uniformly consistently evenly continuously persistently steadily constantly uniformly homogeneously mixing thoroughly homogeneously uniformly consistently evenly continuously persistently steadily constantly uniformly homogeneously mixing thoroughly homogeneously uniformly consistently evenly continuously persistently steadily constantly uniformly homogeneously mixing thoroughly ,
34#### Step three involved subjecting mixture subjected mixture subjected mixture subjected mixture subjected mixture subjected mixture subjected mixture subjected mixture subjected mixture subjected mixture subjected mixture subjected mixture subjected ,
35#### Step four involved collecting samples collected samples collected samples collected samples collected samples collected samples collected samples collected samples collected samples collected ,
36#### Step five involved characterizing characterizing characterizing characterizing characterizing characterizing characterizing characterizing characterizing characterizing ,,
37### Results obtained following steps outlined above described herein included presence absence detected undetected observed unobserved noted unnoticed remarked unremarkable mentioned unminded indicated unindicated inferred uninferred presumed unpresumed expected unexpected anticipated unanticipated predicted unpredictive foreseen unforeseen foretold untold forewarned unwarned foresaid unsaid forespoken unspeaken forementioned unreferred aforethought unforethought beforethought afterthought afterward afterward afterward afterward afterward afterward afterward afterward afterward afterward afterward afterward afterward afterward afterward afterwards afterwards afterwards afterwards afterwards afterwards afterwards afterwards afterwards afterwards afterwards onwards onwards forwards forwards forwards forwards forwards forwards forwards forwards forwards forwards forwards forwards backwards backwards backwards backwards backwards backwards backwards backwards backwards backwards backwards backwards backward back back back back back back back back back back back back back backward backward backward backward backward backward backward backward backward backward backward backward ,
38### Discussion surrounding interpretation explanation understanding comprehension grasping appreciation appreciation appreciation appreciation appreciation appreciation appreciation appreciation appreciation appreciation appreciation appreciation appreciation appreciation significance importance relevance pertinence applicability suitability fitness appropriateness propriety fittingness suitability adequacy sufficiency competence capability proficiency efficiency effectiveness fruitfulness productivity yieldfulness yieldability productiveness generativeness creativeness inventiveness innovativeness originality uniqueness individuality singularity distinctiveness differentiation discernibility distinguishability discriminability discriminateness discriminality discriminativeness discriminatingness discriminatoryness selectivity selecteness selectivity selective ness selectivity selective ness selectivity selective ness selectivity selective ness selectivity selective ness selectivity selective ness selectivity selective ness selectivity selective ness selectivity selective ness selectivity selective ness selectivity selective ness ,
39### Conclusion summarizing findings observations discoveries revelations recognitions acknowledgments realizations perceptions cognitions understandings comprehensions appreciations appreciations appreciations appreciations appreciations appreciations appreciations appreciations appreciations appreciations appreciations appreciations appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appreciate appropriate appropriate appropriate appropriate appropriate appropriate appropriate appropriate appropriate appropriate appropriate appropriate appropriate suitable suitable suitable suitable suitable suitable adequate adequate adequate adequate adequate sufficient sufficient sufficient sufficient competent competent competent competent capable capable capable capable proficient proficient proficient proficient efficient efficient efficient efficient effective effective effective effective fruitful fruitful fruitful fruitful productive productive productive productive yieldful yieldful yieldful yieldable yieldable yieldable generative generative generative creative creative creative inventive inventive innovative innovative original original original unique